Publications du LIME

2017

"High-temperature electron microscopy study of ThO2 microspheres sintering"
G.I. Nkou Bouala, N. Clavier, J. Léchelle, J. Monnier, Ch. Ricolleau, N. Dacheux, R. Podor
J. Europ. Ceram. Soc., 37 (2017) 727.

"Novel approaches for the in situ study of the sintering of nuclear oxide fuel materials and their surrogates"
N. Clavier, G.I. Nkou Bouala, J. Léchelle, J. Martinez, N. Dacheux, R. Podor
Radiochim. Acta, doi:10.1515/ract-2016-2659 (2017).

"Solubility product of the thorium phosphate hydrogenphosphate hydrate (Th2(PO4)2HPO4.H2O, TPHPH)"
D. Qin, S. Szenknect, C. Gausse, A. Mesbah, N. Clavier, N. Dacheux
J. Chem. Therm., doi:10.1016/j.jct.2017.01.003 (2017).

Characterization of thorium aspartate tetrahydrate and comparison of hydrothermal and thermal conversions into ThO2
N. Clavier, J. Maynadié, A. Mesbah, J. Hidalgo, R. Lauwerier, G.I. Nkou Bouala, S. Parrès-Maynadié, D. Meyer, N. Dacheux, R. Podor
J. Nucl. Mater., doi:10.1016/j.jnucmat.2017.02.035 (2017).

 

2016

"Syntheses, Crystal Structures, and Resistivity Studies of Two New Ternary Uranium Selenides, Er3USe8 and Yb3USe8"
J. Prakash, A. Mesbah, J.C Beard, C.D. Malliakas, J.A. Ibers
J. Solid. Stat. Chem. 233 (2016) 90-94.

"Vibrationnal spectroscopy of synthetic analogues of ankoleite, chernikovite and their solid solutions"
N. Clavier, F. Crétaz, S. Szenknect, A. Mesbah, C. Poinssot, M. Descostes, N. Dacheux
Spectrochim. Acta A, 156 (2016) 143-150.

"From in situ HT-ESEM observations to simulation : how does polycristallinity affects the sintering of CeO2 microspheres"
G.I. Nkou Bouala, N. Clavier, S. Martin, J. Léchelle, N. Dacheux, J. Favrichon, H.P. Brau, R. Podor
J. Phys. Chem. C, 120 (2016) 386-395.

First experimental determination of the solubility constant of coffinite
S. Szenknect, A. Mesbah, T. Cordara, N. Clavier, H.P. Brau, X. Le Goff, C. Poinssot, R.C. Ewing, N. Dacheux
Geochim. Cosmochim. Acta 181 (2016) 36-53.

"Charged defects during alpha-irradiation of actinide oxides as revealed by Raman and luminescence spectroscopy"
R. Mohun, L. Desgranges, J. Léchelle, P. Simon, G. Guimbretière, A. Canizarès, F. Duval, C. Jegou, M. Magnin, N. Clavier, N. Dacheux, C. Valot, R. Vauchy
Nucl. Instr. Meth. B 374 (2016) 67-70.

"Syntheses, crystal structure, and electronic properties of the five ABaMQ4 compounds RbBaPS4, CsBaPS4, CsBaVS4, RbBaVSe4, and CsBaVSe4"
A. Mesbah, J. Prakash, D. Rocca, S. Lebègue, J.C. Beard, B.A. Lewis, J.A. Ibers
J. Solid State Chem. 233 (2016) 217-220.

"133Cs and 23Na MAS NMR Spectroscopy of Molybdate Crystallization in Model Nuclear Glasses"
S. Kroeker, S. Schuller, J.E.C. Wren, B.J. Greer, A. Mesbah
J. Am. Ceram. Soc. 99 (2016) 1557-1564.

"Two new ternary chalcogenides Ba2ZnQ3 (Q= Se, Te) with chains of ZnQ4 tetrahedra: syntheses, crystal structure, and optical and electronic properties"
J. Prakash, A. Mesbah, J. Beard, D. Rocca, S. Lebègue, C. Malliakas, J.A. Ibers
Zeit. Natur. B 71 (2016) 425-429

"Coordination Networks Based on Boronate and Benzoxaborolate Ligands"
S. Sene, M.A. Pizzoccaro, J. Vezzani, M. Reinholdt, P. Gaveau, D. Berthomieu, S. Bégu, C. Gervais, C. Bonhomme, G. Renaudin, A. Mesbah, A. van der Lee, M.E. Smith, D. Laurencin
Crystals 6 (2016) 48.

"Preparation, characterization and sintering of yttrium-doped ThO2 for oxygen sensors applications
M. Gabard, Y. Cherkaski, N. Clavier, L. Brissonneau, M.C. Steil, J. Fouletier, A. Mesbah, N. Dacheux
J. All. Compd., 689 (2016) 374.

"The effect of the synthesis route of monazite precursors on the microstructure of sintered pellets
S. Neumeier, Y. Arinicheva, N. Clavier, R. Podor, A. Bukaemskiy, G. Modolo, N. Dacheux, D. Bosbach
Prog. Nucl. Energ., 92 (2016) 298.

Determination of the solubility of rhabdophane LnPO4, 0.667H2O (Ln = La to Dy)
C. Gausse, S. Szenknect, D. Qin, A. Mesbah, N. Clavier, S. Neumeier, D. Bosbach, N. Dacheux
Eur. J. Inorg. Chem., 2016 (2016) 4615.

"Energetics of uranothorite (Th1-xUxSiO4) solid solution"
X. Guo, S. Szenknect, A. Mesbah, N. Clavier, Ch. Poinssot, D. Wu, H. Xu, N. Dacheux, R.C. Ewing, A. Navrotsky
Chem. Mater., 28 (2016) 7117.

"Overview of the crystal chemistry of the actinide chalcogenides: incorporation of the alkaline-earth elements"
A. Mesbah, J. Prakash, J.A. Ibers
Dalton Trans., 45 (2016) 16067.

"Incorporation of Thorium in the Zircon Structure Type through the Th1–xErx(SiO4)1–x(PO4)x Thorite–Xenotime Solid Solution"
A. Mesbah, N. Clavier, J. Lozano-Rodriguez, S. Szenknect, N. Dacheux
Inorg. Chem., doi:10.1021/acs.inorgchem.6b01862, 2016

2015

"The U5+ compound Ba9Ag10U4S24: Synthesis, structure, and electronic properties"
A. Mesbah, W. Stojko, S. Lebègue, C.D. Malliakas, N.L. Frazer, J.A. Ibers
J. Solid State Chem., 221 (2015) 398-404.

"Effects of pH, surface finish and thermal treatment on the corrosion of AlFeNi aluminum alloy. Characterization of oxide layers"
D. Nabhan, B. Kapusta, P. Billaud, K. Colas, D. Hamon, N. Dacheux
J. Nucl. Mater., 457 (2015) 196-204.

"Catalytic Dissolution of Ceria-Lanthanide Mixed Oxides Provides Environmentally Friendly Partitioning of Lanthanides and Platinum"
X. Beaudoux, M. Virot, T. Chave, G. Leturcq, N. Clavier, N. Dacheux, S.I. Nikitenko
Hydrometallurgy151 (2015) 107-115.

"Coordination polymers of uranium (IV) terephthalates"
C. Falaise, A. Assen, I. Mihalcea, C. Volkringer, A. Mesbah, N. Dacheux, T. Loiseau
Dalton Trans., 44 (2015) 2639-2649.

"Dissolution of Th1-xUxO2 : effects of chemical composition and microstructure"
L. Claparede, F. Tocino, S. Szenknect, A. Mesbah, N. Clavier, P. Moisy, N. Dacheux
J. Nucl. Mater., 457 (2015) 304-3016.

"Synthesis, Crystal Structure, Resistivity, Magnetic, and Theoretical Study of ScUS3"
J. Prakash, A. Mesbah, M.D. Ward, S. Lebègue, C.D. Malliakas, M. Lee, E.S. Choi, J.A. Ibers
Inorg. Chem., 54 (2015) 1684-1689.

"Intercalation of Benzoxaborolate Anions in Layered Double Hydroxides: Toward Hybrid Formulations for Benzoxaborole Drugs"
S. Sene, S. Bégu, C. Gervais, G. Renaudin, A. Mesbah, M.E. Smith, P.H. Mutin, A. Van der Lee, J.M. Nedelec, C. Bonhomme, D. Laurencin
Chem. Mater., 27 (2015) 1242-1254

"Syntheses, Crystal Structures, Optical and Theoretical Studies of the Actinide Thiophosphates SrU(PS4)2, BaU(PS4)2, and SrTh(PS4)2"
A. Mesbah, J. Prakash, J.C. Beard, S. Lebègue, C.D. Malliakas, J.A. Ibers
Inorg. Chem., 54 (2015) 2970-2975.

"Positional Flexibility: Syntheses and Characterization of Six Uranium Chalcogenides Related to the 2H Hexagonal Perovskite Family"
A. Mesbah, J. Prakash, J.C. Beard, E.A. Pozzi, M.S. Tarasenko, S. Lebègue, C.D. Malliakas, R.P. Van Duyke, J.A. Ibers
Inorg. Chem., 54 (2015) 2851-2857.

"An Original Precipitation Route toward the Preparation and the Sintering of Highly Reactive Uranium Cerium Dioxide Powders"
J. Martinez, N. Clavier, A. Mesbah, F. Audubert, X.F. Le Goff, N. Vigier, N. Dacheux
J. Nucl. Mater., 462 (2015) 173-181.

"Thermodynamics of formation of coffinite, USiO4"
X. Guo, S. Szenknect, A. Mesbah, S. Labs, N. Clavier, C. Poinssot, S.V. Ushakov, H. Curtius, D. Bosbach, R.C. Ewing, P.C. Burns, N. Dacheux, A. Navrotsky
P. Natl. Acad. Sci. USA, 112 (2015) 6551-6555.

"First report on phosphonate-based homopolymer combining both gadolinium chelating and thermosensitive properties: synthesis and evaluation"
D. Gomes Rodrigues, N. Dacheux, S. Pellet-Rostaing, C. Faur, D. Bouyer, S. Monge
Polym. Chem., 6 (2015) 5264-5272

"Coffinite, USiO4, is abundant in nature : so why it is so difficult to synthesize ?"
A. Mesbah, S. Szenknect, N. Clavier, C. Poinssot, R.C. Ewing, N. Dacheux
Inorg. Chem. 54 (2015) 6687-6696.

"Synthesis, crystal structure, resistivity, and electronic structure of the U(V) quaternary polyselenide Ba8PdU2Se12(Se2)2"
J. Prakash, A. Mesbah, S. Lebègue, C.D. Malliakas, J.A. Ibers
J. Solid State Chem. 230 (2015) 70-74.

"Phase separation and crystallization effects on the structure and durability of molybdenum borosilicate glass"
E. Nicoleau, F. Angeli, S. Schuller, T. Charpentier, P. Jollivet, A. Le Gac, M. Fournier, A. Mesbah, F. Vasconcelos
J. Non-Cryst. Solids 427 (2015) 120-133.

"Crystal Chemistry of Iron Containing Cementitious AFm Layered Hydrates"
G. Renaudin, A. Mesbah, B.Z. Dilnesa, M. François, B. Lothenbach
Current Inorg. Chem. 5 (2015) 184-193.

"Syntheses and characterization of the cubic uranium chalcogenides Rh2U6S15, Cs2Ti2U6Se15, Cs2Cr2U6Se15, and Cs2Ti2U6Te15"
M.D. Ward, G.N. Oh, A. Mesbah, M. Lee, E.S. Choi, J.A. Ibers
J. Solid State Chem. 228 (2015) 14-19.

"Syntheses and Crystal Structures of BaAgTbS3, BaCuGdTe3, BaCuTbTe3, BaAgTbTe3, and CsAgUTe3"
J. Prakash, A. Mesbah, J.C. Beard, J.A. Ibers
Z. Anorg. Allg. Chem. 641 (2015) 1253-1257.

"Three New Quaternary Actinide Chalcogenides Ba2TiUTe7, Ba2CrUTe7, and Ba2CrThTe7: Syntheses, Crystal Structures, Transport Properties, and Theoretical Studies"
J. Prakash, A. Mesbah, J. Beard, S. Lebègue, C.D. Malliakas, J.A. Ibers
Inorg. Chem. 54 (2015 3688–3694.

"Crystal Structures, Transport and Optical Properties, and Theoretical Studies of the Four New Actinide Chalcogenides Ba2Cu4USe6, Ba2Cu2ThSe5, Ba2Cu2USe5, and Sr2Cu2US5"
A. Mesbah, J. Prakash, J.C. Beard, S. Lebègue, C.D. Malliakas, J.A. Ibers
Inorg. Chem. 54 (2015) 9138–9145.

"Characterization of 79Se in UO2 spent nuclear fuel by micro X-ray absorption spectroscopy and its thermodynamic stability"
E. Curti, A. Puranen, D. Grolimund, D. Jädernas, D. Cheptiakov, A. Mesbah, J.A. Ibers
Environ. Sci.: Processes Impacts, 17 (2015) 1760-1768.

"Synthesis, Crystal Structure, Optical, and Electronic Study of the New Ternary Thorium Selenide Ba3ThSe3(Se2)2"
J. Prakash, A. Mesbah, J. C. Beard, S. Lebègue, C. D. Malliakas, J.A. Ibers
J. Solid. Stat. Chem. 231 (2015) 163-168.

"In situ HT-ESEM study of CeO2 nano-ripening : toward a control of nanostructure"
G.I. Nkou Bouala, N. Clavier, J. Léchelle, A. Mesbah, N. Dacheux, R. Podor
Ceram. Intern. 41 (2015) 14703-14711.

"Syntheses, Crystal Structures, and Electronic Properties of Ba8Si2US14 and Ba8SiFeUS14"
A. Mesbah, J. Prakash, S. Lebègue, W. Stojko, J.A. Ibers
Solid State Sci. 48 (2015) 120-124.

"From uranium(IV) oxalate to sintered UO2: consequences of the powders’ thermal history over microstructure"
J. Martinez, N. Clavier, T. Ducasse, A. Mesbah, F. Audubert, B. Corso, N. Vigier, N. Dacheux
J. Eur. Ceram. Soc. 35 (2015) 4535-4546.

2014

"From thorite to coffinite : a spectroscopic study of Th1-xUxSiO4 solid solutions"
N. Clavier, S. Szenknect, D.T. Costin, A. Mesbah, C. Poinssot, N. Dacheux
Spectrochim. Acta A, 118 (2014) 302-307

"Effect of hydration and thermal treatment on ceria surface using non-intrusive techniques"
J. Gaillard, L. Venault, R. Calvet, S. del Confetto, N. Clavier, R. Podor, M. Odorico, J. L. Pellequer, N. Vigier, P. Moisy
J. Nucl. Mater., 444 (2014) 359-367

"Chemical and mineralogical modifications of simplified radioactive waste calcine during heat treatment"
A. Monteiro, S. Schuller, M.J. Toplis, R. Podor, J. Ravaux, N. Clavier, H.P. Brau, T. Charpentier, F. Angeli, N. Leterrier
J. Nucl. Mater.448 (2014) 8-19

"Swelling induced by alpha decay in monazite and zirconolite ceramics: A XRD and TEM comparative study"
X. Deschanels, A.M. Seydoux-Guillaume, V. Magnin, A. Mesbah, M. Tribet, M.P. Moloney, Y. Serruys, S. Peuget
J. Nucl. Mater., 448 (2014) 184-194.

"Dissolution of uranium mixed oxides: the role of oxygen vacancies vs. the redox reactions"
F. Tocino, S. Szenknect, A. Mesbah, N. Clavier, N. Dacheux
Prog. Nucl. Energ., 72 (2014) 101-106.

"High-temperature behavior of Cs2MoO4 in the range of temperature of a fast neutron reactor's surface"
G. Wallez, P.E. Raison, A.L. Smith, N. Clavier, N. Dacheux
J. Solid State Chem., 215 (2014) 225-230.

"Environmental SEM monitoring of Ce1-xLnxO2-x/2 mixed oxides microstructural evolution during dissolution"
D. Horlait, F. Tocino, L. Claparède, N. Clavier, J. Ravaux, S. Szenknect, R. Podor, N. Dacheux
J. Mater. Chem. A, 2 (2014) 5193-5203.

"Preparation and characterisation of uranium oxides with spherical shapes and hierarchical structures"
G.I. Nkou Bouala, N. Clavier, R. Podor, J. Cambedouzou, A. Mesbah, H.P. Brau, J. Lechelle, N. Dacheux
CrystEngComm, 16 (2014) 6944-6954.

"Use of near infrared spectroscopy for the identification of coffinite and uranothorite"
F. Baron, V. Robin, D. Beaufort, S. Szenknect, N. Dacheux, S. Petit
J. Near Infrared Spectrosc., 22 (2014) 149-152.

"The monoclinic form of the rhabdophane compounds: REEPO4 . 0.667 H2O"
A. Mesbah , N. Clavier , E. Elkaim , C. Gausse, I. Benkacem , S. Szenknect , N. Dacheux
Cryst. Growth Des., 14 (2014) 5090-5098.

"Spin-glass state in Ni5(OH)6(CnH2n-4O4)2 metal-organic frameworks (n = 6, 8, 10, 12)"
V. Ban, R. Sibillea, A. Mesbah, T. Gaudisson, T. Mazet, M. François
Solid State Sci., 37 (2014) 154-163.

"Syntheses, Crystal Structures, Transport Properties, and Theoretical Studies of Five Members of the MAn2Q5 Family: SrU2S5, BaU2Se5, PbU2S5, BaTh2S5, and BaU2Te5"
J. Prakash, M.S. Tarasenko, A. Mesbah, S. Lebègue, C.D. Malliakas, J.A. Ibers
Inorg. Chem., 53 (2014) 11626-11632.

2013

9 publications and 1 PhD defense

"Contrôler la microstructure des céramiques nucléaires : de nouveaux outils pour des matériaux adaptables"
N. Clavier, R. Podor, J. Ravaux, G.I. N'kou Bouala, N. Dacheux
L'Actualité Chimique, 380 (déc. 2013) 11-15.

"Solubility properties of synthetic and natural meta-torbernite"
F. Cretaz, S. Szenknect, N. Clavier, P. Vitorge, A. Mesbah, M. Descostes, C. Poinssot, N. Dacheux
J. Nucl. Mater., 442 (2013) 195-207

"The flexible Ba7UM2S12.5O0.5 (M = V,Fe) compounds : syntheses, structures, spectroscopic, resistivity and electronic properties"
A. Mesbah, W. Stojko, C. D. Malliakas, S. Lebègue, N. Clavier, J. A. Ibers
Inorg. Chem., 52 (2013) 12057-12063

"Uranium Carbide Dissolution in Nitric Solution: Sonication vs. Silent Conditions"
M. Virot, S. Szenknect, T. Chave, N. Dacheux, P. Moisy, S. I. Nikitenko
J. Nucl. Mater., 441 (2013) 421-430

"Dilatometric study of U1-xAmxO2±δ and U1-xCexO2± δ reactive sintering"
D. Horlait, A. Feledziak, F. Lebreton, N. Clavier, D. Prieur, N. Dacheux, T. Delahaye
J. Nucl. Mater., 441 (2013) 40-46

"Purification of uranothorite solid solutions from polyphase systems"
N. Clavier, S. Szenknect, D.T. Costin, A. Mesbah, J. Ravaux, C. Poinssot, N. Dacheux
J. Nucl. Mater., 441 (2013) 73-83

"From Uranothorites to Coffinite: A Solid Solution Route to the Thermodynamic Properties of USiO4"
S. Szenknect, D.T. Costin, N. Clavier, A. Mesbah, C. Poinssot, P. Vitorge, N. Dacheux
Inorg. Chem., 52 (2013) 6957-6968

"Combining in situ HT-ESEM observations and dilatometry : an original and fast way to the sintering map of ThO2"
N. Clavier, R. Podor, L. Delière, J. Ravaux, N. Dacheux
Mat. Chem. Phys., 137 (2013) 742-749

"Monazite as a promising long-term radioactive waste matrix: Benefits of high-structural flexibility and chemical durability"
N. Dacheux, N. Clavier, R. Podor
Am. Miner., 98 (2013) 833-847

Thèse ENSCM (ED459) soutenue le 6 décembre 2013 :
« Etude de la solubilité et des cinétiques de dissolution des phosphates et vanadates d’uranium: implications pour l’amont du cycle électronucléaire »
par Fanny Crétaz

2012

13 publications and 1 Ph.D. defense

"Preparation and characterization of synthetic Th0.5U0.5SiO4 uranothorite"
D.T. Costin, A. Mesbah, N. Clavier, S. Szenknect, N. Dacheux, C. Poinssot, J. Ravaux, H.P. Brau
Prog. Nucl. Energ., 57 (2012) 155-160

"Dynamic aspects of CeO2 sintering : HT-ESEM study of grain growth and pore elimination"
R. Podor, N. Clavier, J. Ravaux, L. Claparède, N. Dacheux, D. Bernache-Assollant
J. Eur. Ceram. Soc., 32 (2012) 353-362

"Dissolution of cerium(IV)-lanthanide(III) oxides : comparative effect of chemical composition, temperature and acidity"
D. Horlait, N. Clavier, S. Szenknect, N. Dacheux, V. Dubois
Inorg. Chem., 51 (2012) 3868-3878

"Triclinic-cubic phase transition and negative expansion in the actinide IV (Th, U, Np, Pu) diphosphates"
G. Wallez, P.E. Raison, N. Dacheux, N. Clavier, D. Bykov, L. Delevoye, K. Popa, D. Bregiroux, A. Fitch, R.J.M. Konings
Inorg. Chem., 51 (2012) 4314-4322

"Kinetics of structural and microstructural changes at the solid / solution interface during dissolution of Ce0.4Nd0.6O1.7"
S. Szenknect, A. Mesbah, D. Horlait, N. Clavier, S. Dourdain, J. Ravaux, N. Dacheux
J. Phys. Chem. C, 116 (2012) 12027-12037

"Calcined Resin Microspheres Pelletization (CRMP): a novel process for sintered metallic oxide pellets synthesis"
E. Remy, S. Picart, S. Grandjean, T. Delahaye, N. Herlet, P. Allegri, O. Dugne, R. Podor, N. Clavier, A. Grandjean, P. Blanchart, A. Ayral
J. Europ. Ceram. Soc., 32 (2012) 3199-3209

"Catalytic dissolution of ceria under mild conditions"
M. Virot, T. Chave, D. Horlait, N. Clavier, N. Dacheux, J. Ravaux, S.I. Nikitenko
J. Mater. Chem., 22 (2012) 14734-14740

"Multiparametric study of Th1-xLnxO2-x/2 mixed oxides dissolution in nitric acid media"
D. Horlait, F. Tocino, N. Clavier, N. Dacheux, S. Szenknect
J. Nucl. Mater., 429 (2012) 237-244

"Structure and nuclear density distribution in the cheralite CaTh(PO4)2. Studies of its behaviour under high pressure (36 GPa)"
P.E. Raison, S. Heathman, G. Wallez, C.E. Zvoriste, D. Bykov, G. Ménard, E. Suard, K. Popa, N. Dacheux, R.J.M. Konings, R. Caciuffo
Physics and Chemistry of Minerals, 39 (2012) 685-692

"Synthesis and characterization of Th1-xLnxO2-x/2 mixed-oxides"
D. Horlait, N. Clavier, N. Dacheux, R. Cavalier, R. Podor
Mater. Res. Bull., 47 (2012) 4017-4025

"In situ HT-ESEM observation of CeO2 grain growth during sintering"
R. Podor, N. Clavier, J. Ravaux, L. Claparède, N. Dacheux
J. Am. Ceram. Soc., 95 (2012) 3683-3690

"Physico-chemical characterization and in vivo biological evaluation of pure SiHA for bone tissue engineering application"
D. Marchat, G. Bouët, A. Leckgen, M. Zymelka, L. Malaval, S. Szenknect, N. Dacheux, D. Bernache-Assollant, J. Chevalier
Key Engineering Materials, 530 (2012) 351-356

"Radiation effects in Thorium Phosphate Diphosphate Th4(PO4)4P2O7. A theoretical approach"
C. Meis, N. Dacheux
Mat. Res. Soc. Symp. Proc., 1475 (2012)

Thèse ENSCM (ED459) soutenue le 20 décembre 2012 :
« Solutions solides d'uranothorites : de la préparation à la dissolution »
par Dan Tiberiu Costin

 

2011

9 publications and 2 Ph.D. defenses

Thèse Université Montpellier II (ED459) soutenue le 16 décembre 2011:
« Influence de paramètres physico-chimiques et microstructuraux sur la dissolution d'oxydes mixtes Th1-xUxO2, Th1-xCexO2 et Ce1-xNdxO2-x/2 »
par Laurent Claparède

Thèse Université Montpellier II (ED459) soutenue le 6 décembre 2011:
« Caractérisation structurale d’oxydes mixtes MIV1-xLnIIIxO2-x/2 (M = Ce, Th) préparés par voie oxalique. Etude multiparamétrique de la dissolution et évolution microstructurale. »
par Denis Horlait

"Multiparametric dissolution of thorium-cerium dioxide solid solutions"
L. Claparede, N. Clavier, N. Dacheux, A. Mesbah, J. Martinez, S. Szenknect, Ph. Moisy
Inorg. Chem., 50 (2011) 11702-11714

"How to explain the difficulties in the coffinite synthesis from the study of uranothorite?"
D.T. Costin, A. Mesbah, N. Clavier, N. Dacheux, C. Poinssot, S. Szenknect, J. Ravaux
Inorg. Chem., 50 (2011) 11117-11126

"Negative thermal expansion in Th2O(PO4)2"
G. Wallez, N. Clavier, N. Dacheux, D. Bregiroux
Mat. Res. Bull. 46 (2011) 1777-1780

"Influence of crystallization state and microstructure on the chemical durability of cerium-neodymium mixed dioxides"
L. Claparede, N. Clavier, N. Dacheux, Ph. Moisy, R. Podor, J. Ravaux
Inorg. Chem. 50 (2011) 9059-9072

"Occurrence of an octanuclear motif of uranyl isophthalate with cation-cation interactions through edge-sharing connection mode"
I. Mihalcea, N. Henry, N. Clavier, N. Dacheux and T. Loiseau
Inorg. Chem. 50 (2011) 6243-6249

"Preparation of morphology controlled Th1-xUxO2 sintered pellets from low-temperature precursors"
N. Hingant, N. Clavier, N. Dacheux, S. Hubert, N. Barre, R. Podor and L. Aranda
Powder Tech. 208 (2011) 454-460

"Stability and structural evolution of CeIV1-xLnIIIxO2-x/2 solid solutions: a coupled µ-Raman / XRD approach"
D. Horlait, L. Claparède, N. Clavier, S. Szenknect, N. Dacheux, J. Ravaux and R. Podor
Inorg. Chem. 50 (2011) 7150-7161

"Crystal chemistry of the monazite structure"
N. Clavier, R. Podor and N. Dacheux
J. Eur. Ceram. Soc. 31 (2011) 941-976

"Tetrameric entity resulting from two distinct dinuclear uranyl-centered motifs bridged through mu(2)-OH and pyridazine-3,6-dicarboxylate"
Henry N., Lagrenee M., Loiseau, T, Clavier N., Dacheux N. and Abraham F.
Inorg. Chem. Comm. 14 (2001) 429-432

 

2010

2 publications

"X-Ray diffraction and µ-Raman investigation of the monoclinic-orthorhombic phase transition in Th1-xUx(C2O4)2 2H2O solid solutions"
N. Clavier, N. Hingant, M. Rivenet, S. Obbade, N. Dacheux, N. Barré and F. Abraham
Inorg. Chem. 49 (2010) 1921-1931

"Kinetics of dissolution of thorium and uranium doped britholite ceramics"
N. Dacheux, E. du Fou de Kerdaniel, N. Clavier, R. Podor, J. Aupiais
J. Nucl. Mater. 404 (2010) 33-43

 

2008 - 2009

6 publications

2009

"Preparation, sintering and leaching of optimized uranium thorium dioxides"
N. Hingant, N. Clavier, N. Dacheux, N. Barre, S. Hubert, S. Obbade, F. Taborda and F. Abraham
J. Nucl. Mater. 385 (2009) 400-406

"Corrosion of the AlFeNi alloy used for the fuel cladding in the Jules Horowitz research reactor"
M. Wintergerst, N. Dacheux, F. Datcharry, E. Herms, B. Kapusta
J. Nucl. Mater. 393 (2009) 369-380

"Synthesis and characterization of coffinite"
V. Pointeau, A.P. Deditius, F. Miserque, D. Renock, U. Becker, J. Zhang, N. Clavier, N. Dacheux, C. Poinssot, R.C. Ewing
J. Nucl. Mater. 393 (2009) 449-458

 

2008

"Comparative behavior of britholites and monazite/brabantite solid solutions during leaching tests : a combined experimental and DFT approaches"
E. Veilly, E. du Fou de Kerdaniel, J. Roques, N. Dacheux, N. Clavier
Inorg. Chem. 47 (2008) 10971-10979

"Preparation of optimized uranium and thorium bearing brabantite or monazite/brabantite solid solutions"
O. Terra, N. Dacheux, N. Clavier, R. Podor, F. Audubert
J. Am. Ceram. Soc. 91 (2008) 3673-3682

"Synthesis, Raman and Rietveld analysis of thorium diphosphate"
N. Clavier, G. Wallez, N. Dacheux, D. Bregiroux, M. Quarton, P. Beaunier
J. Solid State Chem. 181 (2008) 3352-3356