Publications du LNER


"Spectrally selective coatings obtained from electrophoretic deposition of CuO nanoparticles." Shehayeb, S.,Deschanels, X.,Karamé, I.,Ghannam, L.,Toquer, G., Surface and Coatings Technology, 322, (2017), 38-45, 10.1016/j.surfcoat.2017.05.028.

"Structuring of Alkyl-Triazole Bridged Silsesquioxanes." Nunes, S. C.,Toquer, G.,Cardoso, M. A.,Mayoral, A.,Ferreira, R. A. S.,Carlos, L. D.,Ferreira, P.,Almeida, P.,Cattoën, X.,Wong Chi Man, M.,de Zea Bermudez, V., ChemistrySelect, 2, (2017), 1, 432-442, 10.1002/slct.2016018

"Synthesis of Poly(diallyldimethylammonium) capped copper hexacyanoferrates (CuHCF) nanoparticles: an efficient stabiliser for Pickering emulsions." Mayer, M.,Dedovets, D.,Guari, Y.,Larionova, J.,Long, J.,Causse, J., Journal of Colloid and Interface Science, (2017), 10.1016/j.jcis.2017.05.113.

"Stable uranium sols as precursors for the elaboration of nanostructured nc-UO2 materials." Leblanc, M.,Causse, J.,Lu, Z.,Rébiscoul, D., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 522, (2017), 18-27,

"Adsorption and separation of hydrocarbons by the metal organic framework MIL-101(Cr)." Belarbi, H.,Boudjema, L.,Shepherd, C.,Ramsahye, N.,Toquer, G.,Chang, J.-S.,Trens, P., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 520, (2017), 46-52,


"Zirconium(IV)–Benzene Phosphonate Coordination Polymers: Lanthanide and Actinide Extraction and Thermal Properties." Luca, V.,Tejada, J. J.,Vega, D.,Arrachart, G.,Rey, C., Inorganic Chemistry, 55, (2016), 16, 7928-7943, 10.1021/acs.inorgchem.6b0

"Reinforced silica monoliths functionalised with metal hexacyanoferrates for Cesium decontamination: A combination of one-pot procedure and skeleton calcination." Sommer-Marquez, A., Mansas, C., Talha, N., Rey, C., Causse, J., Rsc Advances,  6, (2016), 77, 73475-73484, 10.1039/c6ra16980e.

"Study of gradient copolymers self-association in supercritical CO2 thanks to synchrotron and in-house small-angle X-rays scattering measurements", Gasc, F., Corso, B., Lacroix-Desmazes, P., Causse, J., J. Supercrit. Fluids, 114, (2016), 26-31,

"Control of the nanocrystalline zirconia structure through a colloidal sol-gel process." Gossard, A., Grasland, F., Le Goff, X., Grandjean, A., Toquer, G., Solid State Sciences, 55, (2016), 21-28

"Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects." Aréna, H., Godon, N., Rébiscoul, D., Podor, R., Garcès, E., Cabie, M., Mestre, J. P., Journal of Nuclear Materials, 470, (2016), 55-67

"Switchable self-assembly of Prussian blue analogs nano-tiles triggered by salt stimulus." Dedovets, D., Bauduin, P., Causse, J., Girard, L., Diat, O., Physical Chemistry Chemical Physics, (2016)

"Effect of the chemical nature of different transition metal ferrocyanides to entrap Cs." Grandjean, A., Delchet, C., Causse, J., Barré, Y., Guari, Y., Larionova, J., Journal of Radioanalytical and Nuclear Chemistry, 307, (2016), 1, 427-436

"Monolithic zirconia foams synthesis from emulsion stabilized by colloidal clusters." Gossard, A., Toquer, G., Causse, J., Grandjean, A., Chemical Engineering Journal, 285, (2016), 528-535


"Structure evolution of mesoporous silica SBA-15 and MCM-41 under swift heavy ion irradiation." Lou, Y.,Toquer, G.,Dourdain, S.,Rey, C.,Grygiel, C.,Simeone, D.,Deschanels, X., Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 365, Part A, (2015), 336-341,

"Long-term alteration of basaltic glass: Mechanisms and rates." Parruzot, B.,Jollivet, P.,Rébiscoul, D.,Gin, S., Geochimica et Cosmochimica Acta, 154, (2015), 28-48,

"From colloidal precursors to metal carbides nanocomposites MC (M=Ti, Zr, Hf and Si): Synthesis, characterization and optical spectral selectivity studies." Coulibaly, M.,Arrachart, G.,Mesbah, A.,Deschanels, X., Solar Energy Materials and Solar Cells, 143, (2015), 473-479,

"Water Dynamics in Nanoporous Alteration Layer Coming from Glass Alteration: An Experimental Approach." Rebiscoul, D.,Cambedouzou, J.,Briman, I. M.,Cabie, M.,Brau, H. P.,Diat, O., Journal of Physical Chemistry C, 119, (2015), 28, 15982-15993, 10.1021/acs.jpcc.5b03073.

"Overview of Selective Materials and Processes Applied for Decontamination of Nuclear Liquid Wastes ", Barré, Y.,Hertz, A.,Lepeytre, C.,Causse, J.,Schrive, L.,Grandjean, A., Waste Management Proceedings, (2015)

"Strontium selectivity in sodium nonatitanate Na(4)Ti(9)O(20.)xH(2)O." Villard, A., Siboulet, B., Toquer, G.,  Merceille, A., Grandjean, A., Dufreche, J.-F., Journal of Hazardous Materials, 283, (2015), 432-438, doi: 10.1016/j.jhazmat.2014.09.039.

"Simultaneous lanthanides and surfactants micelles removal from aqueous outflows by complexation and sol-gel chemistry", Lavaud, C., Goettmann, F., Grandjean, A., Causse, J., Separation and Purification Technology, 147, (2015), 17-23, doi: 10.1016/j.seppur.2015.02.047

"Elaboration of porous silicon carbide by soft templating molecular precursors with semi-fluorinated alkanes"
T. Nardin, B. Gouze, J. Cambedouzou, P. Bauduin, M. Wong Chi Man,;X. Deschanels, D. Bourgeois, D. Meyer and O. Diat, J. Mater. Chem. A,  3 (2015) 3082 - 3090, DOI: 10.1039/C4TA05996D


 "Effect of 10B(n, α)7Li irradiation on the structure of a sodium borosilicate glass." Peuget, S.,Fares, T.,Maugeri, E. A.,Caraballo, R.,Charpentier, T.,Martel, L.,Somers, J.,Janssen, A.,Wiss, T.,Rozenblum, F.,Magnin, M.,Deschanels, X.,Jégou, C., Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 327, (2014), 22-28,

"Tailoring the Hydrophilic/Lipophilic Balance of Clickable Mesoporous Organosilicas by the Copper-Catalyzed Azide–Alkyne Cycloaddition Click-Functionalization", Langmuir, Achraf Noureddine, Philippe Trens, Guillaume Toquer, Xavier Cattoën and Michel Wong Chi Man, (2014), 30(41), 12297-12305, doi: 10.1021/la503151w

"High-internal phase emulsions stabilized by colloidal Zr-based solid clusters." Gossard, A.,Toquer, G.,Grandjean, A.,Causse, J., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 462, (2014), 0, 162-169, doi: 10.1016/j.colsurfa.2014.09.007.

"A General Method for Preparing Bridged Organosilanes with Pendant Functional Groups and Functional Mesoporous Organosilicas", K. Burglova, A. Noureddine, J. Hodacova, G. Toquer, X. Cattoen, M.W.C. Man, Chemistry-a European Journal, 20, (2014), 10371, doi: 10.1002/chem.201403136

"Coupling between SAXS and Raman spectroscopy applied to the gelation of colloidal zirconium oxy-hydroxide systems", A. Gossard, G. Toquer, S. Grandjean, A. Grandjean, Journal of Sol-Gel Science and Technology, 71, (2014), 571, doi: 10.1007/s10971-014-3409-2

"Facile one-pot synthesis of copper hexacyanoferrate nanoparticles functionalised silica monoliths for the selective entrapment of 137Cs", Causse, J., Moloney, M. P., Tokarev, A., Ravaux, J., Barre, Y., & Grandjean, A. (2014). . Journal of Materials Chemistry A., 2(25), 9461-9464 doi:10.1039/C4TA01266F

"Sodium “Activation” of Silano-Phosphonate Modified Mesoporous TiO2 Leading to Improved Rare-Earth Element Extraction. European Journal of Inorganic Chemistry"  Moloney, M. P., Causse, J., Loubat, C., & Grandjean, A. (2014). Eur. J. Inorg. Chem., 13, 2268-2277, doi: 10.1002/ejic.201400027

"Investigation of the local environment of iodate in hydroxyapatite by combination of X-ray absorption spectroscopy and DFT modeling." Laurencin, D., Vantelon, D., Briois, V., Gervais, C., Coulon, A., Grandjean, A., & Campayo, L. (2014).  Rsc Advances, 4(28), 14700-14707. doi: 10.1039/c3ra47691j

"Swelling induced by alpha decay in monazite and zirconolite ceramics: A XRD and TEM comparative study." Deschanels, X., Seydoux-Guillaume, A. M., Magnin, V., Mesbah, A., Tribet, M., Moloney, M. P., Serruys, Y., & Peuget, S. (2014).  J. Nuc. Mat., 448(1-3), 184-194, doi:10.1016/j.jnucmat.2014.02.003

"Submicron coating of SiO2 nanoparticles from electrophoretic deposition." Charlot, A., Deschanels, X., & Toquer, G. (2014).  Thin Solid Films, 553, 148-152. doi: 10.1016/j.tsf.2013.11.064

"Nanocomposites derived from silica and carbon for low temperature photothermal conversion."  Charlot, A., Bruguier, O., Toquer, G., Grandjean, A., & Deschanels, X. (2014).  Thin Solid Films, 553, 157-160. doi: 10.1016/j.tsf.2013.10.111

"Effect of aging and alkali activator on the porous structure of a geopolymer." Steins, P., Poulesquen, A., Frizon, F., Diat, O., Jestin, J., Causse, J., Lambertin, D., & Rossignol, S. (2014).  Journal of Applied Crystallography, 47, 316-324. doi: 10.1107/s160057671303197x


"An Original "Click and Bind" Approach for Immobilizing Copper Hexacyanoferrate Nanoparticles on Mesoporous Silica"  Turgis, R., Arrachart, G., Delchet, C., Rey, C., Barre, Y., Pellet-Rostaing, S., Guari, Y., Larionova, J., & Grandjean, A. (2013). Chemistry of Materials, 25(21), 4447-4453. doi: 10.1021/cm4029935

"Comparison of two soft chemistry routes for the synthesis of mesoporous carbon/beta-SiC nanocomposites."   Deschanels, X., Herault, D., Arrachart, G., Rey, C., Grandjean, A., Toquer, G., Podor, R., Zemb, T., Cerveau, G., & Corriu, R. (2013).  Journal of Materials Science, 48(11), 4097-4108. doi: 10.1007/s10853-013-7222-z


"Mesoporous materials in the field of nuclear industry: applications and perspectives"
Philippe Makowski, Xavier Deschanels, Agnès Grandjean, Daniel Meyer, Guillaume Toquer and Frédéric Goettmann.
New Journal of Chemistry, 36 (2012), 531-541

"Surface Diels–Alder Reactions as an Effective Method to Synthesize Functional Carbon Materials"
Helena Kaper, Agnès Grandjean, Claudia Weidenthaler, Ferdi Schüth, and Frédéric Goettmann.
Chemistry, A European Journal, 18 (2012), 4099-4106

"Radiation damage of mesoporous silica thin films monitored by X ray reflectivity and Scanning electron microscopy"
S. Dourdain, X. Deschanels, G. Toquer, C. Grygiel, I. Monnet, S. Pellet-Rostaing, A. Grandjean
Journal of Nuclear Materials, 477 (2012), 411-414.

"Extraction of Radioactive Cesium Using innovative functionalized porous materials"
C. Delchet, A. Tokarev, X. Dumail, G. Toquer, Y. Barré, Y. Guari, Ch. Guérin, J. Larionova, and A. Grandjean
RSC Advances,  2 (2012), 5707-5716.

"The sorption behaviour of synthetic sodium nonatitanate and zeolite A for removing radioactive strontium from aqueous wastes"
Aurélie Merceille, Evelyne Weinzaepfel, Yves Barré, Agnès Grandjean,
Separation and Purification Technology, 96 (2012), 81-88.

"Macroporous LTA-monoliths for in-flow removal of radioactive strontium from aqueous effluents: Application to the case of Fukushima"
Alexander Sachse, Aurélie Merceille, Yves Barré, Agnès Grandjean, François Fajula, Anne Galarneau,
Microporous and Mesoporous Materials, 164  (2012),  251–25.

"Stability of mesoporous silica under acidic conditions"
Sabah El Mourabit, Marie Guillot, Guillaume Toquer, Julien Cambedouzou, Frédéric Goettmann and
Agnès Grandjean,
RSC Advances, 2 (2012) 10916-10924



"Incorporation of iodates into hydroxyapatites: a new approach for the confinement of radioactive iodine"
Lionel Campayo, Agnès Grandjean, Antoine Coulon, Rémy Delorme, Delphine Vantelon and Danielle Laurencin.
J. Mater. Chem, 21 (2011), 17609-17611.

"The mechanism of the hydrothermal alteration of cerium- and plutonium-doped zirconolite"
P. Poml, T. Geisler, J. Cobos-Sabate, T.  Wiss, P.E. Raison, P. Schmid-Beurmann, X. Deschanels, C. Jegou, J. Heimink and A. Putnis
J. Nucl Mat., 410 (1-3)  2011 pp 10-23

"Effect of the synthesis temperature of sodium nonatitanate on batch kinetics of strontion ion adsorption from aqueous solution"
Aurélie Merceille, Evelyne Weinzaepfel, Yves Barré, Agnès Grandjean
Adsorption, 17 (2011), 967-975.

"Wall thickness prediction in precipitated precursors of mesoporous materials"
Agnès Grandjean, Guillaume Toquer, Thomas Zemb
Journal of Physical Chemistry C, (2011), 115 (23), pp 11525–11532

"Helium diffusion in curium-doped borosilicate waste glass"
T. Fares, S. Peuget, O. Bouty, X. Deschanels, C. Jégou
Journal of Nuclear Materials416 (2011) 236-241.

"Effect of leaching concentration and time on the morphology of pores in porous glasses"
Guillaume Toquer, Carole Delchet, Mathieu Nemec, Agnès Grandjean
Journal of Non-Crystalline Solids, 357 (2011) 1552-1557



"Volatilization kinetics of sulphur from borosilicate melts: A correlation between sulphur diffusion and melt viscosity"
Marion Lenoir, Daniel R. Neuville, Mohammed Malki, Agnès Grandjean,
Journal of Non-Crystalline Solids, 356 (2010) 2722-2727

"Ionic physisorption on bubbles induced by pulsed ultra-sound"
G. Toquer, T. Zemb, D. Shchukin, H. Mohwald,
Physical Chemistry Chemical Physics, 12 (2010) 14553-14559

"Synthesis of Carbide Compounds Derived from Colloidal Oxide and Carbohydrate"
X. Deschanels, M. El Ghazzal, C. Delchet, D. Herault, V. Magnin, A. Grandjean, R. Podor, G. Cerveau, T. Zemb, R. Corriu,
Progress in Colloid Polymere Science, 137, 2010, 47-52

"Hydrothermal synthesis of imidazole functionalized carbon spheres and their application in catalysis"
R. Demir Cakan, P Makowski, M. Antonietti, F. Goettmann, MM Titrici,
Catalysis Today, 150 2010, 115-118

"Mechanism of Metal Oxide Nanoparticle Loading in SBA-15 by the Double Solvent Technique"
van der Meer J., Bardez-Giboire I., Mercier C., Revel B., Davidson A. and Denoyel R.
J. Phys. Chem. C, 114(8) 2010 pp 3507-3515

"Toward a Low-Temperature Sol-Gel Synthesis of TiO2(B) Using Mixtures of Surfactants and Ionic Liquids"
Kaper H., Sallard S., Djerdj I., Antonietti M. and Smarsly BM.
Chem. Mat., 22(11) 2010 pp 3502-3510

"Characterization of mesoporous Materials using Small-Angle Scattering (SAXS/SANS)"
"Charakterisierung mesoporöser Materialien mittels Kleinwinkelstreuung (SAXS/SANS)"
Smarsly BM., Kaper H., Mascotto S. and Weidmann C.
Chemie. Ingieur. Techik. 82(6) 2010 pp 823-828

"Functionalized porous glass for the removal and the confinement of ruthenium from radioactive solutions"
Alexei Tokarev, Agnès Grandjean, Yannick Guari, Joulia Larionova, Rachel Pflieger, Christian Guérin
Journal of Nuclear Materials, 400 (2010) 25-31


2007 - 2009


"Chlorine borrowing: an efficient method for an easier use of alcohols as alkylation agents"
P. Makowski, R. Rothe, A. Thomas, M. Niederberger, F. Goettmann
Green Chem. 2009, 34-37

"Chloride ion pairs as catalysts for the alkylation of aldehydes and ketones with C–H acidic compounds"
C. Carrignon, P. Makowski, M. Antonietti, F. Goettmann
Tetrahedron Lett. 2009 4833-4837

"Synthesis of Early-Transition-Metal Carbide and Nitride Nanoparticles through the Urea Route and Their Use as Alkylation Catalysts"
W. Yoa, P. Makowski, C. Giordano, F. Goettmann
Chem. Eur. J. 2009 11999-12004

"Potentialities of fluoride-based salts for specific nuclear reprocessing: Overview of the R&D program at CEA"
Lacquement J., Boussier H., Laplace A., Conocar O., Grandjean A.
Journal of fluorine chemistry, vol 130, Issue 1, Sp. Iss. SI, 18-21, (2009)

"Structure of borosilicate glasses and melts: a Raman spectroscopy study"
Dario Manara, Grandjean Agnès, Daniel R. Neuville
American Mineralogist, 94: (2009) 777-784

"Electrical Conductivity of RuO2–Borosilicate Glasses: Effect of the Synthesis Route"
Rachel Pflieger, Mohamed Malki, Yannick Guari, Joulia Larionova, Agnès Grandjean
Journal of the American Ceramic Society, 92 (2009) 1560-1566

"Quantitation of sulfate solubility in borosilicate glasses using Raman spectroscopy"
Marion Lenoir, Agnès Grandjean, S. Poissonnet, Daniel R. Neuville
Journal of Non Crystalline Solids, 355 (2009) 1468-1473

"Structure of borosilicate glasses and melts: A revision of the Yun, Bray and Dell model"
Dario Manara, Agnès Grandjean, Daniel R. Neuville
Journal of Non Crystalline Solids, 355 (2009) 1468-1473

"Organic materials for hydrogen storage applications: from physisorption on organic solids to chemisorption in organic molecules"
P. Makowski, A. Thomas, P. Kuhn, F. Goettmann
Energy Environ. Sci. 2009, 480-490

"Behavior of ruthenium dioxide in borosilicate glasses and melts"
R. Pflieger, L. Lefebvre, M. Malki, M. Allix, A. Grandjean
Journal of Nuclear Materials, 389, 2009, 450-457

"Advances in the structure understanding of borosilicate glasses: a Raman spectroscopy study"
D. Manara, A. Grandjean, D.R. Neuville
American Mineralogist, 94, 2009, pp777-784

"Comparing two ceramics waste forms in term of alpha decay induced structural changes"
Deschanels X., Magnin V., Peuget S., Seydoux-Guillaume M., Glorieux B.
39eme journées des actinides, 28-31 mars 2009, la Grande Motte (France)



"High surface area TiO2 and TiN as noble metal free catalysts for the C-C coupling of alcohols and ketones"
A. Fischer, P. Makowski, J.O. Müller, M. Antonietti, A. Thomas, F. Goettmann
ChemSusChem. 2008, 444-449

"Metal-free activation of C-C multiple bonds through halide ion pairs: Diels-Alder reactions with subsequent aromatization"
H. Kaper, M. Antonietti, F. Goettmann
Tetrahedron Lett. 2008, 4546-4549

"A mesoporous poly(benzimidazole) network as a purely organic heterogeneous catalyst for the Knoevenagel condensation"
P. Makowski, J. Weber, A. Thomas, F. Goettmann
Catal. Commun. 2008, 243-247

"The influence of Si,B substitution and of the nature of network-modifying cations on the properties and structure of borosilicate glasses and melts"
M. Lenoir, A. Grandjean, D. R. Neuville
Chemical Geology, 256(3-4), 2008 p. 316-325

"Low temperature synthesis of carbide powders"
X. Deschanels, C. Delchet, D. Herault, V. Magnin, O. Diat, A. Grandjean, R. Podor, T. Zemb
Nanosmat 2008, 21-24 October 2008 Barcelona (Espagne)

"Ion beam radiation effects in monazite"
V. Picot, X. Deschanels, S. Peuget et al.
Journal of Nuclear Materials, 381-3, 2008, 290-296



"Influence of processing conditions on the class-crystal transition into glasses"
X. Deschanels, JN. Cachia, C. Lopez, T. Charpentier
Cost D43 Meeting, March 19-21 2007, Cracow (Poland).